Preheat oven to 350 degrees. Spray 10 muffin cups with nonstick baking spray with flour. Set aside.
Cut biscuits into thirds. Pour melted butter into a medium bowl. In another medium bowl, stir together sugars and cinnamon. Dip biscuit pieces into butter, then dredge in sugar mixture. Place 3 biscuits pieces into each muffin cup.
Bake until puffed and golden brown, 12 to 15 minutes. Let stand 5 minutes. Run a knife around edge of cups; remove rolls. Drizzle with maple syrup.