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Preheat oven to 350 degrees. Grease 9-by-13-inch pan with cooking spray.
Chop onion and bell pepper. Remove stems from broccoli florets.
Heat medium-sized frying pan over medium heat. Add oil and swirl around pan. Add onions and cook 3–4 minutes until they start to soften. Add broccoli and bell pepper. Mix with onions and add salt and pepper, to taste. Cook 1–2 minutes, then cover to steam another 2–3 minutes until broccoli is bright green. Remove veggies from stovetop.
In large mixing bowl, beat eggs. Add cottage cheese, shredded cheese, baking powder and flour. Add veggies and salt and pepper, to taste. Transfer to prepared pan and bake 40 minutes.
Fully cooked casserole will store for 2-3 months in the freezer. Thaw and reheat in a low-temp oven until warmed througout.